Thursday, September 19, 2019

Chemical Processing of Plastic Waste – Pyrolysis


In a previous July 12, 2019 blog (click here to read), I provided some data on the amount of plastic waste globally generated each year and how much of it is recycled, either by mechanical or chemical processes.

In this blog, I am identifying four chemical companies that are developing one of the chemical methods – pyrolysis – for recycling plastic waste (other chemical methods, e.g., solvolysis and gasification, will be written about in future blogs).  Extensively searching the Internet, I could find that four of the fifty largest global chemical companies (the fifty being based on the 2018 Chemical and Engineering News report identifying the top fifty; click here to read report) have pilot investigations of technologies and processes for recycling waste plastics using pyrolysis.  The following is a brief description of what each is doing:

BASF, at the pilot plant level, has generated new plastics from the cracking of pyrolysis oil.  The pyrolysis oil was provided by Recenso.   The plastics are being tested by BASF partners who might be eventual buyers of the plastics.  So far, the plastics have been meeting necessary use standards. 

Dow has signed an agreement with the Dutch company Fuenix Ecology Group to buy pyrolysis oil from Fuenix.  Fuenix produces the pyrolysis oil from waste plastics.  Dow will process the oil into new polymers at its Terneuzen, Netherlands plant.  Dow has a goal of incorporating 100,000 metric tons of pyrolysis oil into its plastic production by 2025. 

Ineos Styrolution, a subsidiary of Ineos, has entered into a joint development agreement with Agilyx for a recycling plant at its polystyrene plant in Illinois.  Agilyx’s pyrolysis process for recycling waste polystyrene will be used at the plant.

Sabic is investigating the introduction of volumes of pyrolysis oil feedstock, provided to it by the company Plastic Energy, into Sabic’s cracker at Geleen, the Netherlands, producing polyethylene and polypropylene.  The pyrolysis oil was produced by Plastic Energy from mixed plastic wastes.

It is interesting that each of the four companies have agreements with other, smaller companies to provide the pyrolysis oil.  This suggests the need for agreements with various contributors in a complex undertaking that recycling plastics appears to be.  It also might be a strategy that serves the larger companies well, in case recycling plastic wastes by pyrolysis does not develop into a successful business for these companies. 

An excellent report from BCG (Boston Consulting Group), entitled “A Circular Solution to Plastic Waste”, is summarized at this link.  The full report can be read by clicking here (pdf file).  This report identifies well the challenges, advantages, economics, and other aspects of the chemical processing of plastics waste by pyrolysis.


Thursday, September 5, 2019

Chemical Companies Interests in Products for Energy Storage


Due to a rapid increase globally in generating electricity by intermittent renewable energy sources, a need exists for energy storage systems, which can store the generated electrical energy until it is used as electricity.   Several energy storage systems are used but recently the most prevalent system being put into operation is battery storage, and the battery system most often used is based on lithium-ion technologies.

Because chemical technologies are critical to battery energy storage (as well as other types of energy storage), I researched the Internet for chemical company products and activities related to energy storage.  The following table summarizes what I found:


product
chemical company
arkema (binders)

lanxess (high purity nickel and cobalt compounds)

ppg industries

ptt global chemical

sk innovation

solvay

sumitomo chemical
cathodes (lithium-ion batteries)
arkema (binders)

formosa plastics (including lithium-iron phosphorous oxide cathodes)

lanxess (high purity nickel and cobalt compounds)

ptt global chemical

sk innovation 

solvay

sumitomo chemical
cryogenic air separation technology to store energy in form of cryogenic liquids
air liquide

air products and chemicals
electrolytes (lithium-ion batteries)
arkema (fluorine-based)

dupont (joint venture with ube industries)

lanxess 

ptt global chemical

solvay 

sumtomo chemical
flame retardants for battery use
lanxess
flow battery technology
basf

lotte chemical

sabic (joint venture with schmid to develop vanadium redox flow batteries
hydrogen as energy storage projects
air liquide

linde
lithium sulfur batteries
ptt global chemical
lithium-air batteries
ptt global chemical
lithium-ion battery packs
hatachi chemical

lg chem

sk innovation
materials (miscellaneous for use in batteries)
basf (porous carbon materials)

covestro (polycarbonate blends)

evonik (redox polymer materials for use in battery cells to power small electronic circuits)

lanxess (high tech polyamides and polyester for use in batteries)

lanxess (raw materials for synthesis of lithium compounds)

ppg industries (coatings)

sabic (joint venture for developing nano-technologies for use in energy storage systems)

sk innovation (cell packaging)

solvay (fluorinated materials)
separators (lithium-ion batteries)
arkema (coatings)

asahi kasei (1.55 billion meter square of polyolefin film by 2021)

dupont (nano fiber-based polymeric materials)

mitsui chemical (special polymeric materials)

ptt global chemical

sk innovation

solvay (specialized polymers)

sumitome chemical (aramid-polyolefins)

toray (building factory in hungary to manufacturer separators)
sodium-sulfur batteries
basf 
solid state batteries
ptt global chemical
thermal energy storage using salts
linde



The above table indicates to me a strong interest by chemical companies in providing products supporting energy storage.  This is not surprising given the expected high demand for energy storage, especially battery energy storage, in the coming years.  It is also not surprising because of the relevancy of what chemical companies can offer and the dependency of energy storage developments on chemical technologies, materials, and standards.

More details on the needs of energy storage in the coming years are provided by a US Energy Information Administration report (click here; pdf file); an International Renewable Energy Agency report (click here; pdf file); and an Energy Storage World Forum report (click here; pdf file).







Sunday, September 1, 2019

Chemical and Metal Shortage Alert – August 2019


The purpose of this blog is to identify chemical and metal shortages reported on the Internet.  The sources of the information reported here are primarily news releases issued on the Internet.  The issue period of the news releases is August 2019.

Section I below lists those chemicals and metals that were on the previous month’s Chemical and Metal Shortage Alert list and continue to have news releases indicating they are in short supply. Click here to read the July 2019 Chemical and Metal Shortage Alert list.

Section II lists the new chemicals and metals (not on the July alert).  Also provided is some explanation for the shortage and geographical information.  This blog attempts to list only actual shortage situations – those shortages that are being experienced during the period covered by the news releases.  Chemicals and metals identified in news releases as only being in danger of being in short supply status are not listed.

Section I.

None

Section II.   Shortages Reported in August not found on the Previous Month’s List

Pipe-grade high density polyethylene (HDPE):  Russia; production not keeping up with demand

Reasons for Section II shortages can be broadly categorized as: 

1.  Mining not keeping up with demand: none
2.  Production not keeping up with demand: Pipe-grade high density polyethylene (HDPE)
3.  Government regulations: none
4.  Sources no longer available: none
5.  Insufficient imports:  none
6.  Supply not keeping up with demand: none